
Product Name: Optical Brightener OB-1 / Fluorescent Brightener 393
Chemical Name: 2,2′-(1,2-Ethenediyldi-4,1-phenylene)bisbenzoxazole
Color Index: C.I. 393
CAS: 1533-45-5
Molecular Formula: C₂₈H₁₈N₂O₂
Formula Weight: 414.45 g/mol
Synonyms: Fluorescent Brightener 393; OB-1; 2,2′-(4,4′-Diphenylvinyl)dibenzoxazole; Fluorescent Whitening Agent OB-1; Optical Brightening Agent OB-1; Bisbenzoxazole Derivative; FBA 393
Application:
Polyester Fibers, Nylon Fibers, Polypropylene Fibers, Engineering Plastics (ABS, PS, HIPS, PC, PA, PET, PBT), PVC, PP, PE, EVA, Masterbatch, Clear Lacquers, Paints, Printing Inks, Coatings, Plastic Recycling, Synthetic Leather, Photoelectric Communication Materials
1. Product Description
Achieve Unparalleled Whiteness with Optical Brightener OB-1 – The Premium High-Temperature Fluorescent Brightener.
Optical Brightener OB-1, internationally designated as Fluorescent Brightener 393 (C.I. 393), represents the pinnacle of bisbenzoxazole-based optical brightener chemistry . This sophisticated compound is specifically engineered for applications requiring exceptional thermal stability and brilliant whitening performance under demanding processing conditions. Unlike conventional optical brighteners that degrade at elevated temperatures, OB-1 maintains its integrity throughout high-temperature polymer processing, making it the definitive choice for engineering plastics and synthetic fiber applications.
At the molecular level, OB-1 functions through a sophisticated photophysical mechanism. The bisbenzoxazole structure acts as a conjugated chromophore system that absorbs invisible ultraviolet radiation in the 340-380 nm range and re-emits it as visible blue-violet light (approximately 400-450 nm) . This fluorescence phenomenon effectively masks the inherent yellowness of polymer substrates while simultaneously imparting a brilliant, "whiter-than-white" appearance that enhances the perceived brightness and aesthetic quality of the final product.
What truly distinguishes Optical Brightener OB-1 is its extraordinary combination of thermal stability and polymer compatibility. With a melting point of 355-360°C and excellent stability during melt processing, OB-1 withstands the rigorous conditions of injection molding, extrusion, and fiber spinning without decomposition or sublimation . Its hydrophobic molecular structure ensures excellent dispersion and solubility within the polymer matrix, creating a permanent brightening effect that is integral to the material itself—not merely a surface treatment .
Our Optical Brightener OB-1 is manufactured under strict quality controls, offering ≥99% purity with consistent batch-to-batch performance. The product is available in two distinct crystalline forms—greenish-yellow and yellowish-green—each offering slightly different shade characteristics (blue vs. blue-violet fluorescence) to accommodate diverse aesthetic requirements . This versatility, combined with its exceptional performance profile, has established OB-1 as the industry benchmark for high-value plastic and fiber whitening applications.
2.Product Specifications (Technical Data Sheet)
| Property | Specification | Insight |
| Product Name | Optical Brightener OB-1 (Fluorescent Brightener 393) | Premium bisbenzoxazole brightener for high-temperature applications . |
| Appearance | Bright Yellowish-Green to Light Green Uniform Powder | Fine, free-flowing powder; available in green and yellow crystalline forms . |
| CAS No. | 1533-45-5 | Verified chemical registry number . |
| EINECS/EC No. | 216-245-3 | Listed in European inventory . |
| Solubility | Insoluble in water; soluble in organic solvents (chlorobenzene, dichlorobenzene, DMSO, DMF, toluene) | Hydrophobic nature ensures excellent polymer compatibility . |
| Style | Bisbenzoxazole / Fluorescent Whitening Agent (FBA) | Non-ionic, heat-stable brightener for polymers and fibers. |
| Tinting Strength | High | Exceptional whitening efficacy with minimal dosage . |
| Purity | ≥ 98.5% - 99.5% (HPLC) | High purity ensures consistent performance and minimal impurities . |
| Melting Point | 355-360°C (decomposes) | Exceptionally high thermal stability for high-temperature processing . |
| Fluorescence λmax | 400-450 nm (blue to blue-violet emission) | Characteristic blue-violet fluorescence for optimal whitening effect . |
| UV Absorption Range | 340-380 nm | Efficient absorption of near-UV radiation . |
| Volatility | Low | Minimal sublimation during processing; non-migrating in end products . |
| pH (1% solution) | pH > 7 (yellow form) / pH < 7 (green form) | Different crystalline forms offer distinct pH characteristics . |
| Packing | 25 kg fiber drums with double PE inner liners; 500 kg jumbo bags; custom sizes available | Secure, moisture-proof packaging to maintain product integrity . |
| Storage Conditions | Store in cool, dry place; protect from direct sunlight; keep containers tightly closed | Stable for extended periods under proper storage conditions . |
| Application | Polyester fibers, Nylon fibers, PP fibers, Engineering plastics (ABS, PS, PC, PA, PET), PVC, PE, EVA, Masterbatch, Coatings, Inks | Versatile across multiple industries |
3. Product Application (Industry Usage Guide)
Synthetic Fibers (Polyester, Nylon, Polypropylene):
Optical Brightener OB-1 is the industry-standard whitening agent for man-made fibers, offering permanent brightening effects that are incorporated directly into the fiber during manufacturing . Application methods include:
Polyester Fibers (PET): Applied during polymerization or via masterbatch addition; dosage 75-300 grams per 1000 kg of substrate. OB-1 effectively masks the inherent yellowish cast of polyester and imparts brilliant whiteness with excellent lightfastness .
Polyester-Cotton Blends: Provides exceptional whitening on blended fabrics where the brightener migrates primarily to the polyester component, creating a harmonious overall whiteness .
Nylon Fibers (Polyamide): Used during polymerization or as a spinning additive; dosage 75-200 grams per 1000 kg of substrate. OB-1 offers superior heat stability for nylon processing temperatures .
Polypropylene Fibers (PP): Effective for both fiber and non-woven applications with good thermal stability and compatibility .
Engineering Plastics & Thermoplastics:
OB-1's exceptional thermal stability (melting point >350°C) makes it the preferred brightener for high-temperature engineering plastics that require melt processing at elevated temperatures.
Masterbatch & Color Concentrates:
Optical Brightener OB-1 is highly suitable for incorporation into masterbatch formulations. Its excellent compatibility with carrier resins and thermal stability during compounding ensures uniform distribution and consistent whitening performance. Available in both green and yellow crystalline forms to meet specific shade requirements .
Plastic Recycling:
OB-1 demonstrates exceptional value in recycling applications. When added to recycled polyester waste materials, bottle flakes, and regrind, the brightener effectively restores whiteness and improves the aesthetic quality of recycled polymers, often achieving whiteness levels comparable to virgin materials . This application is particularly valuable for closed-loop recycling initiatives and sustainable manufacturing practices.
Dosage Recommendations:
Transparent Applications: 0.0001-0.001% (1-10 grams per 1000 kg) – minimal addition for subtle clarity enhancement
White/Solid Applications: 0.01-0.05% (10-50 grams per 1000 kg) – typical range for optimal whitening effect
Engineering Plastics: 0.0075-0.03% (75-300 grams per 1000 kg) – depending on polymer type and desired whiteness level
Processing Considerations:
Suitable for incorporation via masterbatch, direct compounding, or polymerization addition
Optimal dispersion achieved through high-shear mixing during melt processing.
No special handling or processing modifications required; compatible with standard manufacturing equipment.
Permanent brightening effect as the brightener is dissolved within the polymer matrix, offering superior durability compared to surface treatments.
Safety & Handling:
Optical Brightener OB-1 is classified with GHS warning labels: H315 (skin irritation), H319 (eye irritation), H335 (respiratory irritation) . Appropriate personal protective equipment (gloves, safety glasses, dust mask) should be used during handling. Avoid dust formation and ensure adequate ventilation. Store in cool, dry conditions away from direct sunlight.